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3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID


  • CAS
  • Purity
  • 499-02-5
  • 99%
Inquiry

Cosmetics Grade 3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID 499-02-5 For Sale with Good Price

  • Molecular Formula: C6H6 O4
  • Molecular Weight: 142.111
  • Vapor Pressure: 0.000145mmHg at 25°C 
  • Melting Point: 197-201 °C 
  • Refractive Index: 1.5800 (estimate) 
  • Boiling Point: 309.2°Cat760mmHg 
  • PKA: 3.48±0.40(Predicted) 
  • Flash Point: 155°C 
  • Density: 1.49g/cm3 

3-METHYLENECYCLOPROPANE-TRANS-1,2-DICARBOXYLIC ACID(Cas 499-02-5) Usage

InChI:InChI=1/C6H6O4/c1-2-3(5(7)8)4(2)6(9)10/h3-4H,1H2,(H,7,8)(H,9,10)/p-2/t3-,4-/m1/s1

499-02-5 Relevant articles

Synthesis of some C2-symmetric bidentate ligands and their complexes derived from Feist's acid

Al-Majid, Abdullah M. A.,Al-Othman, Zeid A.,Islam, Mohammad Shahidul

experimental part, p. 268 - 277 (2012/04/10)

Various new C2-symmetric bidentate ligan...

Synthesis and characterization of some new c2 symmetric chiral bisamide ligands derived from chiral feist's acid

Al Majid, Abdullah M.A.,Islam, Mohammad Shahidul,Al-Othman, Zeid Abdullah,Al-Salhoob, Ahlam F.,Barakat, Assem

scheme or table, p. 5550 - 5563 (2012/08/28)

The hemilabile chiral C2 symmetrical bid...

C2-Symmetric Ligands for Asymmetric Catalysis based on Feist's Acid

Al-Maijd, Abdullah,Booth, Brian L. M.,Gomes, Jonnes T.

, p. 580 - 589 (2007/10/03)

(2R,3R)-(+)-Feist's acid has been conver...

Process for the preparation of an antiviral agent

-

, (2008/06/13)

Racemic Feist's acid is treated with (R)...

499-02-5 Process route

ethyl 3-bromo-4,6-dimethyl-2-oxo-2H-pyran-5-carboxylate
18152-79-9

ethyl 3-bromo-4,6-dimethyl-2-oxo-2H-pyran-5-carboxylate

Feist's acid
499-02-5

Feist's acid

Conditions
Conditions Yield
With potassium hydroxide; In 1,4-dioxane; at 105 ℃; for 0.833333h;
68%
With potassium hydroxide; Heating;
ethyl acetoacetate
141-97-9

ethyl acetoacetate

Feist's acid
499-02-5

Feist's acid

Conditions
Conditions Yield
ethyl acetoacetate; With hydrogenchloride; for 336h; Darkness;
With bromine; In chloroform; at 20 ℃; for 24h;
With potassium hydroxide; at 105 ℃; for 1h;
19%

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    ethyl 3-bromo-4,6-dimethyl-2-oxo-2H-pyran-5-carboxylate

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    (+/-)-methylene-cyclopropane-1r ,2t -dicarbonyl chloride

  • 499-02-5
    499-02-5

    (1R,2R)-(+)-3-methylenecyclopropane-1,2-dicarboxylic acid

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